The first entity in the rebooted Collector's Vault series, the first disc is functionally similar to the previous four volumes in the Collector's Choice series name. Disc 1 by itself is internally named "Collector's Choice Volume 5."

To counter one of the common complaints that major characters were generally only left to weaker shorts, a second disc of shorts that hasn't been on Blu-ray in a mainline Looney Tunes home media disc was implemented. Commentaries are left out if they were originally included in previous releases, but this came at the reward of a higher video and audio bitrate. This allowed some 1998 dubbed versions and I Love Tweety prints to get new prints for the HD resolution, so they look entirely different than in previous incarnations. "Porky's Duck Hunt", previously an orphan short that was only available in the out of print Essential Daffy Duck DVD and on the divisive Porky 101 DVD set was finally found an official new home with various restored shorts, allowing collector's to take less of a risky jump just for one short. One of the main complaints of the Platinum Collection, being the excessive use of double dipping to upgrade shorts to HD, has been resolved with a much better split between the new to disc and the double dip upgrades.

Due to an error, one short was mistakenly double dipped from a previous Collector's Choice volume, being "Double or Mutton". Only by the time the set was finalized that this error was noticed; Warner Archive remedied this by providing 26 cartoons on disc 1 on the next volume.

"A Day at the Zoo", "Of Fox and Hounds", and "Each Dawn I Crow" are newly restored for this set. All Tweety shorts (except "Red Riding Hoodwinked") are upgrades from their previous I Love Tweety and Golden Collection incarnations, being entirely re-restored for the HD resolution with less DVNR. Any other shorts on disc 1 are from their 2020 restorations used for streaming and television, while the disc 2 shorts are previous shorts that were never made available on official HD home media with minor touchups.